Metallic tin quantum sheets confined in graphene toward high-efficiency carbon dioxide electroreduction
نویسندگان
چکیده
Ultrathin metal layers can be highly active carbon dioxide electroreduction catalysts, but may also be prone to oxidation. Here we construct a model of graphene confined ultrathin layers of highly reactive metals, taking the synthetic highly reactive tin quantum sheets confined in graphene as an example. The higher electrochemical active area ensures 9 times larger carbon dioxide adsorption capacity relative to bulk tin, while the highly-conductive graphene favours rate-determining electron transfer from carbon dioxide to its radical anion. The lowered tin-tin coordination numbers, revealed by X-ray absorption fine structure spectroscopy, enable tin quantum sheets confined in graphene to efficiently stabilize the carbon dioxide radical anion, verified by 0.13 volts lowered potential of hydroxyl ion adsorption compared with bulk tin. Hence, the tin quantum sheets confined in graphene show enhanced electrocatalytic activity and stability. This work may provide a promising lead for designing efficient and robust catalysts for electrolytic fuel synthesis.
منابع مشابه
Graphene Oxide/Polyaniline-Based Multi Nano Sensor for Simultaneous Detection of Carbon Dioxide, Methane, Ethanol and Ammonia Gases
In this study, a multi nanosensor was fabricated for the simultaneous detection of carbon dioxide, methane, ethanol, and ammonia gases, and its electrochemical response to various concentrations of these gases were investigated. In order to fabricate this multi nanosensor, in the first phase, the Graphene-Oxide/Polyaniline (GO/PANI) nanocomposite was synthesized. Chemical ...
متن کاملA metal-free electrocatalyst for carbon dioxide reduction to multi-carbon hydrocarbons and oxygenates
Electroreduction of carbon dioxide into higher-energy liquid fuels and chemicals is a promising but challenging renewable energy conversion technology. Among the electrocatalysts screened so far for carbon dioxide reduction, which includes metals, alloys, organometallics, layered materials and carbon nanostructures, only copper exhibits selectivity towards formation of hydrocarbons and multi-ca...
متن کاملGeometric Effects on Nanopore Creation in Graphene and on the Impact-withstanding Efficiency of Graphene Nanosheets
Abstract Single- and multilayer graphene sheets (MLGSs) are projectile-resisting materials that can be bombarded by nanoparticles to produce graphene sheets of various sizes and distributions of nanopores. These sheets are used in a variety of applications, including DNA sequencing, water desalination, and phase separation. Here, the impact-withstanding efficiency of graphene nanosheets and the...
متن کاملAnalytical quantum current modeling in GNSFET
Carbon nanoscrolls (CNSs) belong to the same class of carbon-based nanomaterialsas carbon nanotubes. As a new category of quasi one dimensional material Graphene Nanoscroll (GNS) has captivated the researchers recently because of its exceptional electronic properties like having large carrier mobility. GNS shape has open edges and no caps unlike Single Wall Nanotubes (SWNTs) which are wou...
متن کاملCarbon nanotube/graphene nanocomposite as efficient counter electrodes in dye-sensitized solar cells.
We demonstrated the replacement of the Pt catalyst normally used in the counter electrode of a dye-sensitized solar cell (DSSC) by a nanocomposite of dry spun carbon multi-walled nanotube (MWNT) sheets with graphene flakes (Gr-F). The effectiveness of this counter electrode on the reduction of the triiodide in the iodide/triiodide redox (I(-)/I(3)(-)) redox reaction was studied in parallel wit...
متن کامل